منابع مشابه
Stereospecific Synthesis of Tri- and Tetrasubstituted α-Fluoroacrylates by Mizoroki-Heck Reaction.
Ligand-free, efficient, palladium-catalyzed Mizoroki-Heck reaction between methyl α-fluoroacrylate and arene or hetarene iodides is reported for the first time. The reaction is stereospecific and provides fair to quantitative yields of fluoroalkenes. The Mizoroki-Heck reaction starting from more hindered and usually reluctant trisubstituted acrylate, to access tetrasubstituted fluoroalkenes, is...
متن کاملStereospecific synthesis of amphetamines
Regioselective addition of aryl lithium to commercially available (S)-(+)-propylene oxide provides the corresponding (S)-aryl-2-propanol. The (R)-amphetamine is obtained by conversion of the alcohol to the tosylate followed by azide displacement and hydrogenation. Mitsunobu conversion of the alcohol to the (R)-bromide followed by azide displacement and hydrogenation affords the (S)-amphetamine....
متن کاملA Stereospecific Analysis of Triglycerides.
A method is presented for the analysis of the fatty acid compositions in each of the three positions of a triglyceride. Diglycerides are obtained from the triglyceride by lipolysis with pancreatic lipase, and converted to a mixture of Dand L-phosphatidyl phenol. The L-phosphatide is then hydrolyzed by phospholipase A, leaving a lysophosphatide with the fatty acid in position 1, free fatty acid ...
متن کاملStereospecific Constructions of Chiral > Lactams
I. Amino Acids A. Alkylamino Acids: :-Alkylamino acids, L-proline, L-valine. B. Hydroxyamino Acids: L-Serine, L-threonine, D-allothreonine, L-isoserine. C. Amino-amino Acids: L-2,3-Diaminopropionic acid, L-2,4-diaminobutyric acid. D. Carboxyamino Acids: L-Aspartic acid, 3-amino-pentanedioic acids. E. Thioamino Acids: D-Penicillamine, DOr L-methylcysteine, L-cysteine, L-methionine. F. Amido-amin...
متن کاملStereospecific studies on carotenoid biosynthesis.
Various species of [2-14C] MVA stereospecifically labelled with tritium at C-2, C-4 and C-5 have been used to study details of carotenoid biosynthesis in a variety of preparations including chioroplasts, fruit and root slices, and fungi. Mechanisms have been proposed for the dimerization of geranylgeranyl pyrophosphate to form phytoene, for the cyclization of acyclic precursors to form aand a-c...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1965
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.68.5_741